Flashcards: Chemistry Revision Map — 60 cards

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1Question

How does a strong acid differ from a weak acid in dissociation?

Answer

A strong acid dissociates completely, a weak acid establishes an equilibrium.

2Question

How many H⁺ ions can a diprotic acid donate?

Answer

Two H⁺ ions.

3Question

What is the formula for the acid dissociation constant Kₐ?

Answer

Kₐ = [H⁺][A⁻] / [HA].

4Question

How is acidity pKₐ related to Kₐ?

Answer

pKₐ = -log Kₐ.

5Question

What is the formula relating amount, concentration, and volume?

Answer

n = c × V.

6Question

What is the dilution formula relating concentrations and volumes?

Answer

c₁V₁ = c₂V₂.

7Question

What is the condition at the equivalence point in a 1:1 titration?

Answer

Amount of acid equals amount of base.

8Question

What is the equivalence pH of a strong acid–strong base titration?

Answer

Equivalence pH is 7.

9Question

Where does oxidation occur in an electrochemical cell?

Answer

Oxidation occurs at the anode.

10Question

What happens to electrons during reduction?

Answer

Reduction gains electrons.

11Question

What charge does the anode have in a galvanic cell?

Answer

The anode is negative.

12Question

What role does the cathode play in a galvanic cell?

Answer

The cathode uses electrons.

13Question

In which direction do electrons flow in a galvanic cell?

Answer

Electrons flow from the anode to the cathode.

14Question

Where do salt-bridge anions migrate in a galvanic cell?

Answer

Anions migrate to the anode.

15Question

What is reduced at the cathode during molten NaCl electrolysis?

Answer

Sodium ions (Na⁺) are reduced to sodium.

16Question

What is oxidised at the anode during molten NaCl electrolysis?

Answer

Chloride ions are oxidised to chlorine.

17Question

What happens when a reactant is added to a system at equilibrium?

Answer

Equilibrium shifts toward products.

18Question

How does adding a product affect the equilibrium position?

Answer

Equilibrium shifts toward reactants.

19Question

What effect does increasing pressure have on gaseous equilibrium?

Answer

It shifts equilibrium toward fewer gas particles.

20Question

How does decreasing pressure influence gaseous equilibrium?

Answer

It shifts equilibrium toward more gas particles.

21Question

Which direction does increasing temperature favor in a reaction?

Answer

The endothermic direction.

22Question

What direction does decreasing temperature favor in a reaction?

Answer

The exothermic direction.

23Question

What is the formula for the equilibrium constant Kc?

Answer

Kc = [products]^(coefficients) divided by [reactants]^(coefficients).

24Question

What does Kc > 1 indicate about equilibrium?

Answer

Products are favored at equilibrium.

25Question

What functional group does C=C represent?

Answer

Alkene

26Question

What functional group does –OH represent?

Answer

Alcohol

27Question

What functional group does –COOH represent?

Answer

Carboxylic acid

28Question

How does an alkene react with bromine?

Answer

By addition across the C=C bond

29Question

What does a primary alcohol oxidise to first?

Answer

An aldehyde.

30Question

What does a secondary alcohol oxidise to?

Answer

A ketone.

31Question

What is produced by reduction of a nitrile?

Answer

An amine.

32Question

What functional group does an ester contain?

Answer

R–COO–R.

33Question

What distinguishes structural isomers?

Answer

Different connectivity with the same molecular formula.

34Question

What defines E/Z isomers?

Answer

A C=C bond with different groups on both carbons and different spatial arrangement.

35Question

What IR absorption range identifies alcohol O–H groups?

Answer

3200–3600 cm⁻¹ broad absorption.

36Question

Which IR absorption range indicates carboxylic-acid O–H groups?

Answer

2500–3000 cm⁻¹ very broad absorption.

37Question

What IR absorption near 1700 cm⁻¹ identifies a C=O group?

Answer

A strong peak approximately at 1700 cm⁻¹.

38Question

What does a strong 1700 cm⁻¹ peak with a broad 2500–3000 cm⁻¹ peak indicate?

Answer

A carboxylic acid.

39Question

What does a 1700 cm⁻¹ peak without O–H absorption indicate?

Answer

An aldehyde or ketone.

40Question

What is the highest molecular peak in a mass spectrum called?

Answer

The molecular ion M⁺.

41Question

When is an amino acid positively charged based on pH and pI?

Answer

When pH is less than pI.

42Question

Which direction do positive ions move during electrophoresis?

Answer

Toward the negative electrode.

43Question

Which intermolecular force is stronger: hydrogen bonding or dipole–dipole?

Answer

Hydrogen bonding is stronger than dipole–dipole forces.

44Question

How do OH, COOH, and NH₂ groups affect solubility in water?

Answer

They increase solubility through hydrogen bonding with water.

45Question

Which ion moves to the cathode in an acidic hydrogen fuel cell?

Answer

H⁺ ions move to the cathode.

46Question

Which ion moves to the anode in an alkaline hydrogen fuel cell?

Answer

OH⁻ ions move to the anode.

47Question

Where do electrons travel in a hydrogen fuel cell?

Answer

Electrons travel through the external circuit.

48Question

Where do ions travel in a hydrogen fuel cell?

Answer

Ions travel through the electrolyte.

49Question

What is the formula for atom economy (AE)?

Answer

AE = (M_r of desired product ÷ M_r of all reactants) × 100.

50Question

Is a higher or lower atom economy better?

Answer

A higher atom economy is better.

51Question

What is the formula for the E-factor?

Answer

E = waste ÷ product.

52Question

Is a higher or lower E-factor better?

Answer

A lower E-factor is better.

53Question

What formula calculates moles from concentration and volume?

Answer

n = c × V

54Question

How do you calculate concentration from moles and volume?

Answer

c = n ÷ V

55Question

Which formula relates concentrations and volumes in dilution?

Answer

c₁V₁ = c₂V₂

56Question

How is pH calculated from hydrogen ion concentration?

Answer

pH = -log[H⁺]

57Question

What is the formula for pKa in terms of Ka?

Answer

pKa = -log Ka

58Question

What are the three steps for answering Calculate questions?

Answer

Write formula, substitute values, give answer with units

59Question

What three elements must Justify responses include?

Answer

Claim, relevant data, and chemical reasoning

60Question

What does a three-mark short response require?

Answer

Prediction, chemical reason, and evidence or data

Test yourself with the quiz

Test your knowledge with 33 questions on Chemistry Revision Map.

1. How does a weak acid differ from a strong acid in aqueous solution?

2. How many protons can a diprotic acid donate per molecule?

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