Flashcards: Chemistry Revision Map — 60 cartões

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1Pergunta

How does a strong acid differ from a weak acid in dissociation?

Resposta

A strong acid dissociates completely, a weak acid establishes an equilibrium.

2Pergunta

How many H⁺ ions can a diprotic acid donate?

Resposta

Two H⁺ ions.

3Pergunta

What is the formula for the acid dissociation constant Kₐ?

Resposta

Kₐ = [H⁺][A⁻] / [HA].

4Pergunta

How is acidity pKₐ related to Kₐ?

Resposta

pKₐ = -log Kₐ.

5Pergunta

What is the formula relating amount, concentration, and volume?

Resposta

n = c × V.

6Pergunta

What is the dilution formula relating concentrations and volumes?

Resposta

c₁V₁ = c₂V₂.

7Pergunta

What is the condition at the equivalence point in a 1:1 titration?

Resposta

Amount of acid equals amount of base.

8Pergunta

What is the equivalence pH of a strong acid–strong base titration?

Resposta

Equivalence pH is 7.

9Pergunta

Where does oxidation occur in an electrochemical cell?

Resposta

Oxidation occurs at the anode.

10Pergunta

What happens to electrons during reduction?

Resposta

Reduction gains electrons.

11Pergunta

What charge does the anode have in a galvanic cell?

Resposta

The anode is negative.

12Pergunta

What role does the cathode play in a galvanic cell?

Resposta

The cathode uses electrons.

13Pergunta

In which direction do electrons flow in a galvanic cell?

Resposta

Electrons flow from the anode to the cathode.

14Pergunta

Where do salt-bridge anions migrate in a galvanic cell?

Resposta

Anions migrate to the anode.

15Pergunta

What is reduced at the cathode during molten NaCl electrolysis?

Resposta

Sodium ions (Na⁺) are reduced to sodium.

16Pergunta

What is oxidised at the anode during molten NaCl electrolysis?

Resposta

Chloride ions are oxidised to chlorine.

17Pergunta

What happens when a reactant is added to a system at equilibrium?

Resposta

Equilibrium shifts toward products.

18Pergunta

How does adding a product affect the equilibrium position?

Resposta

Equilibrium shifts toward reactants.

19Pergunta

What effect does increasing pressure have on gaseous equilibrium?

Resposta

It shifts equilibrium toward fewer gas particles.

20Pergunta

How does decreasing pressure influence gaseous equilibrium?

Resposta

It shifts equilibrium toward more gas particles.

21Pergunta

Which direction does increasing temperature favor in a reaction?

Resposta

The endothermic direction.

22Pergunta

What direction does decreasing temperature favor in a reaction?

Resposta

The exothermic direction.

23Pergunta

What is the formula for the equilibrium constant Kc?

Resposta

Kc = [products]^(coefficients) divided by [reactants]^(coefficients).

24Pergunta

What does Kc > 1 indicate about equilibrium?

Resposta

Products are favored at equilibrium.

25Pergunta

What functional group does C=C represent?

Resposta

Alkene

26Pergunta

What functional group does –OH represent?

Resposta

Alcohol

27Pergunta

What functional group does –COOH represent?

Resposta

Carboxylic acid

28Pergunta

How does an alkene react with bromine?

Resposta

By addition across the C=C bond

29Pergunta

What does a primary alcohol oxidise to first?

Resposta

An aldehyde.

30Pergunta

What does a secondary alcohol oxidise to?

Resposta

A ketone.

31Pergunta

What is produced by reduction of a nitrile?

Resposta

An amine.

32Pergunta

What functional group does an ester contain?

Resposta

R–COO–R.

33Pergunta

What distinguishes structural isomers?

Resposta

Different connectivity with the same molecular formula.

34Pergunta

What defines E/Z isomers?

Resposta

A C=C bond with different groups on both carbons and different spatial arrangement.

35Pergunta

What IR absorption range identifies alcohol O–H groups?

Resposta

3200–3600 cm⁻¹ broad absorption.

36Pergunta

Which IR absorption range indicates carboxylic-acid O–H groups?

Resposta

2500–3000 cm⁻¹ very broad absorption.

37Pergunta

What IR absorption near 1700 cm⁻¹ identifies a C=O group?

Resposta

A strong peak approximately at 1700 cm⁻¹.

38Pergunta

What does a strong 1700 cm⁻¹ peak with a broad 2500–3000 cm⁻¹ peak indicate?

Resposta

A carboxylic acid.

39Pergunta

What does a 1700 cm⁻¹ peak without O–H absorption indicate?

Resposta

An aldehyde or ketone.

40Pergunta

What is the highest molecular peak in a mass spectrum called?

Resposta

The molecular ion M⁺.

41Pergunta

When is an amino acid positively charged based on pH and pI?

Resposta

When pH is less than pI.

42Pergunta

Which direction do positive ions move during electrophoresis?

Resposta

Toward the negative electrode.

43Pergunta

Which intermolecular force is stronger: hydrogen bonding or dipole–dipole?

Resposta

Hydrogen bonding is stronger than dipole–dipole forces.

44Pergunta

How do OH, COOH, and NH₂ groups affect solubility in water?

Resposta

They increase solubility through hydrogen bonding with water.

45Pergunta

Which ion moves to the cathode in an acidic hydrogen fuel cell?

Resposta

H⁺ ions move to the cathode.

46Pergunta

Which ion moves to the anode in an alkaline hydrogen fuel cell?

Resposta

OH⁻ ions move to the anode.

47Pergunta

Where do electrons travel in a hydrogen fuel cell?

Resposta

Electrons travel through the external circuit.

48Pergunta

Where do ions travel in a hydrogen fuel cell?

Resposta

Ions travel through the electrolyte.

49Pergunta

What is the formula for atom economy (AE)?

Resposta

AE = (M_r of desired product ÷ M_r of all reactants) × 100.

50Pergunta

Is a higher or lower atom economy better?

Resposta

A higher atom economy is better.

51Pergunta

What is the formula for the E-factor?

Resposta

E = waste ÷ product.

52Pergunta

Is a higher or lower E-factor better?

Resposta

A lower E-factor is better.

53Pergunta

What formula calculates moles from concentration and volume?

Resposta

n = c × V

54Pergunta

How do you calculate concentration from moles and volume?

Resposta

c = n ÷ V

55Pergunta

Which formula relates concentrations and volumes in dilution?

Resposta

c₁V₁ = c₂V₂

56Pergunta

How is pH calculated from hydrogen ion concentration?

Resposta

pH = -log[H⁺]

57Pergunta

What is the formula for pKa in terms of Ka?

Resposta

pKa = -log Ka

58Pergunta

What are the three steps for answering Calculate questions?

Resposta

Write formula, substitute values, give answer with units

59Pergunta

What three elements must Justify responses include?

Resposta

Claim, relevant data, and chemical reasoning

60Pergunta

What does a three-mark short response require?

Resposta

Prediction, chemical reason, and evidence or data

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1. How does a weak acid differ from a strong acid in aqueous solution?

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